ASYMMETRIC INDUCTION IN FREE RADICAL ADDITION OF THIOLS TOl-MENTHYL CROTONATE
نویسندگان
چکیده
منابع مشابه
Chiral-Sc catalyzed asymmetric Michael addition/protonation of thiols with enones in water.
Asymmetric Michael reactions and enantioselective protonations between enones and thiols were catalyzed by a Sc(OTf)(3)-chiral 2,2'-bipyridine complex in water. The remarkable governing of the enantioselectivity for simple introduction of protons despite their abnormally high mobility in water may provide us with new synthetic opportunities as well as significant chemical advances.
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1980
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1980.195